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optical brightenerPF(OBA135)

2,2'-vinylenebis[5-methylbenzoxazole]

CAS: 1041-00-5;12224-12-3

Molecular Formula: C18H14N2O2

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optical brightenerPF(OBA135) - Names and Identifiers

Name 2,2'-vinylenebis[5-methylbenzoxazole]
Synonyms Optical Brightener PF
OPTICAL BRIGHTENER 135
FLUOESCENT BRIGHTENER-PF
Fluorescent Brightener PF
Fluorescent brightener 135
Fluorescent brightener PF-3
optical brightenerPF(OBA135)
Optical Brightening Agent PF
Optical Brightening Agent PF-3
C.I. Fluorescent Brightener 135
Fluorescent brightening agent 135
1,2-di(5-mythyl-benziazolyl)ethylene
Fluorescent brightener PF for plastic
2,2'-vinylenebis[5-methylbenzoxazole]
Optical Brightening Agent PF C. I. 135
2,2-ethene-1,2-diylbis(5-methyl-1,3-benzoxazole)
2,2-(E)-ethene-1,2-diylbis(5-methyl-1,3-benzoxazole)
5-methyl-2-[(E)-2-(5-methyl-1,3-benzoxazol-2-yl)ethenyl]-1,3-benzoxazole
CAS 1041-00-5
12224-12-3
EINECS 602-366-2
InChI InChI=1/C18H14N2O2/c1-11-3-5-15-13(9-11)19-17(21-15)7-8-18-20-14-10-12(2)4-6-16(14)22-18/h3-10H,1-2H3/b8-7+

optical brightenerPF(OBA135) - Physico-chemical Properties

Molecular FormulaC18H14N2O2
Molar Mass290.31596
Density1.287g/cm3
Melting Point180-181℃
Boling Point471.2°C at 760 mmHg
Flash Point237.3°C
Vapor Presure1.35E-08mmHg at 25°C
pKa2.87±0.10(Predicted)
Storage Condition2-8℃
Refractive Index1.727
Physical and Chemical PropertiesThe milky white slurry with good dispersibility is neutral. It belongs to non ionic compounds. Melting point 182~184 ℃. Insoluble in water, soluble in DMF and ethanol, acid resistant to pH 2-3, and alkali resistant to pH around 10. Resistant to hard water to 5 × 10-4. The optimal dyeing temperature is 150 ℃ (in a neutral or weakly alkaline bath), which can withstand roasting at 180-200 ℃. Its slurry and diluent are not sensitive to light.
UseUsed for polyester film, polyvinyl chloride, polypropylene, ABS, organic glass and other whitening

optical brightenerPF(OBA135) - Upstream Downstream Industry

Raw MaterialsPolyoxyethylene lauryl ether
Poly(vinyl alcohol)
L-(-)-Malic Acid
DL-Malic acid
2-Amino-p-cresol

optical brightenerPF(OBA135) - Reference

Reference
Show more
1. He Zhihua, Zuo Junfeng, Xiong Majian, Zhu Bijun. Determination of Fluorescent Whitening Agents in Pharmaceutical Composite Films by High Performance Liquid Chromatography [J]. Journal of Drug Analysis, 2020,40(09):1645-1652.

optical brightenerPF(OBA135) - safety

Open Data Verified Data

This product can be managed according to general industrial chemicals. When using it, gloves and protective glasses should be worn to avoid direct contact with the skin and eyes. If it gets on the skin, rinse with water and soap. Place in a cool and dry warehouse to prevent exposure to sunlight and rain.

 

Last Update:2023-10-20 09:14:42

optical brightenerPF(OBA135) - Preparation method

Open Data Verified Data

Firstly, 33 portions of xylene were injected into the reactor, followed by 3.5 portions of o-aminop-cresol, 2.0 portions of hydroxysuccinic acid, and 0.1 portions of boric acid. Carbon dioxide was introduced and heated to boiling under stirring. Reflux for 12 hours, and use a water separator to separate the generated water during the reaction. After the reaction is completed, cool down to 130 ℃, add activated carbon, stir and heat for reflux for half an hour, filter, cool the filtrate to 15 ℃, precipitate crystals, and dry to obtain the crude product. Put the crude product, water, and polyvinyl alcohol together into a sand mill to grind to a certain fineness, then add an appropriate amount of leveling agent O, formaldehyde, polyvinyl alcohol solution, etc., and stir thoroughly to obtain the finished product (the dosage in preparation is the mass fraction).

 

Last Update:2024-01-02 23:10:35

optical brightenerPF(OBA135) - Nature

EPA chemical information Benzoxazole, 2,2'-(1,2-ethenediyl)bis[5-methyl- (1041-00-5)
Last Update:2024-04-10 22:29:15

optical brightenerPF(OBA135) - Uses and synthesis methods

chemical properties

this product is a milky white slurry with good dispersibility and is neutral. It is a non-ionic compound. Melting point 182~184 ℃. Insoluble in water, soluble in DMF and ethanol, acid resistance to pH = 2~3, alkali resistance to pH = 10 or so. Hard water resistance to 5 × 10-4. The best dyeing temperature is 150 ℃ (in neutral or weak alkaline bath) and can withstand roasting at 180~200 ℃. Its slurry and diluent are not sensitive to light.

use

1. This product is used as a whitening agent for synthetic fibers, and is suitable for whitening polyester, nylon, acetate or synthetic fibers, cotton, wool blended fabrics, etc. The fabric with it is effective in good light fastness and moisture fastness.

2. Used as a whitening agent for polyester, polyamide, acetate and blended fabrics

production method

first, 33 parts of xylene are put into the reaction kettle, then 3.5 parts of o-amino p-cresol, 2.0 parts of hydroxysuccinic acid and 0.1 parts of boric acid are added, carbon dioxide is introduced, and heated to boiling under stirring. After 12 h of reflux, the water separator is used to separate the generated water in the reaction. After the reaction is completed, the temperature is reduced to 130 ℃, activated carbon is put in, stirred, heated and refluxed for half an hour, filtered, the filtrate is cooled to 15 ℃, crystallized, and dried to obtain crude products.

P> put the crude product, water and polyvinyl alcohol into sand grinding to a certain fineness, then add appropriate amount of leveling agent O, formaldehyde, polyvinyl alcohol solution, etc., and fully stir to obtain the finished product (the feeding amount in preparation is mass fraction).

Last Update:2024-04-10 22:29:15
optical brightenerPF(OBA135)
Supplier List
Shanghai Macklin Biochemical Co., Ltd
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Product Name: 1,2-Bis(5-methyl-2-benzoxazolyl)ethylene Visit Supplier Webpage Request for quotation
CAS: 1041-00-5
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SKYRUN INDUSTRIAL CO.,LTD
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Hefei TNJ Chemical Industry Co.,Ltd.
Product Name: 2,2'-vinylenebis[5-methylbenzoxazole] Request for quotation
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Shanghai Yuanye Bio-Technology Co., Ltd.
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Product Name: Fluorescent Brightener 135,2,2-(1,2-Ethenediyl)Bis[5-Methylbenzoxazole] Visit Supplier Webpage Request for quotation
CAS: 1041-00-5
Tel: 18301782025
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Shanghai Macklin Biochemical Co., Ltd
Featured ProductsSpot supply
Product Name: 1,2-Bis(5-methyl-2-benzoxazolyl)ethylene Visit Supplier Webpage Request for quotation
CAS: 1041-00-5
Tel: +86-18821248368
Email: Int06@meryer.com
Mobile: +86-18821248368
QQ: 495145328 Click to send a QQ message
WhatsApp: +86-18821248368
Guangzhou Yuanda New Material Co.,Ltd
Multiple Specifications
Product Name: Fluorescent Brightener 135 Request for quotation
CAS: 1041-00-5
Tel: +86 19849939632
Email: 2470479589@qq.com
Mobile: +86 19849939632
QQ: 2470479589 Click to send a QQ message
Shanghai Amole Biotechnology Co., Ltd.
Spot supply
Product Name: 1,2-Bis(5-methylbenzo[d]oxazol-2-yl)ethene Request for quotation
CAS: 1041-00-5
Tel: 400-968-2212
Email: 3623107365@qq.com
Mobile: 18916960931
QQ: 3623107365 Click to send a QQ message
Wechat: 18916960931
SHANGHAI ACMEC BIOCHEMICAL TECHNOLOGY CO., LTD.
Spot supply
Product Name: 1,2-Bis(5-methyl-2-benzoxazolyl)ethylene Visit Supplier Webpage Request for quotation
CAS: 1041-00-5
Tel: +86-400-900-4166
Email: product@acmec-e.com
Mobile: +86-18621343501
QQ: 2881950922 Click to send a QQ message
Wechat: 18621343501
WhatsApp: +86-18621343501
MedChemExpress (MCE)
Multiple SpecificationsSpot supply
Product Name: Fluorescent Brightener 135 Visit Supplier Webpage Request for quotation
CAS: 1041-00-5
Tel: 609-228-6898
Email: sales@medchemexpress.com
     tech@medchemexpress.com
Mobile: 609-228-6898
SKYRUN INDUSTRIAL CO.,LTD
Multiple SpecificationsSpot supply
Product Name: FLUOESCENT BRIGHTENER-PF Visit Supplier Webpage Request for quotation
CAS: 1041-00-5
Tel: +86 0571-86722205
Email: sales@chinaskyrun.com
Mobile: +8618958170122
QQ: 2531159185 Click to send a QQ messageSend QQ message
Wechat: chinaskyrun
Hefei TNJ Chemical Industry Co.,Ltd.
Product Name: 2,2'-vinylenebis[5-methylbenzoxazole] Request for quotation
CAS: 1041-00-5
Tel: 0086-551-65418684
Email: sales@tnjchem.com
     info@tnjchem.com
Mobile: 0086 189 4982 3763
QQ: 2881500840 Click to send a QQ message
Wechat: 189 4982 3763
WhatsApp: 0086 189 4982 3763
Product List: View Catalog
Shanghai Yuanye Bio-Technology Co., Ltd.
Spot supply
Product Name: Fluorescent Brightener 135,2,2-(1,2-Ethenediyl)Bis[5-Methylbenzoxazole] Visit Supplier Webpage Request for quotation
CAS: 1041-00-5
Tel: 18301782025
Email: 3008007409@qq.com
Mobile: 18021002903
QQ: 3008007409 Click to send a QQ message
View History
optical brightenerPF(OBA135)
105-44-2
Raw Materials for optical brightenerPF(OBA135)
Polyoxyethylene lauryl ether
Poly(vinyl alcohol)
L-(-)-Malic Acid
DL-Malic acid
2-Amino-p-cresol
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